You open an energy lesson and run into ΔT, Δm and ΔᵣH°. It looks as if someone fell on the keyboard. Not so: they’re three simple ideas, and secondary-school maths is more than enough to follow them.
Δ Delta: what changed
- Say it
- “delta” or “change in”. ΔT is read “change in temperature”.
- It means
- Δ in front of something is how much it changed: the final value minus the starting value.
Δ is the capital D of the Greek alphabet, the D of “difference”. If water goes from 18 °C to 25 °C, ΔT = 25 − 18 = 7 °C. If it cools from 25 °C to 18 °C, ΔT = 18 − 25 = −7 °C. The sign tells you which way the change went: positive if it rose, negative if it fell.
Real example · in the lesson Joules, watts or calories? Energy and power without fear
ΔT = Q / (m · c): how much the temperature rises for the heat Q you put in.
Real example · in the lesson Can you make something from nothing? Conservation, no fear
Δm = E / c²: the mass that disappears when an energy E is released.
Eₐ Subscripts: the label underneath
- Say it
- Eₐ is read “E sub a” or, better, by its name: “activation energy”.
- It means
- The small letter or number at the bottom right is a label: it says what that quantity is. It doesn't multiply or raise anything.
Science has lots of energies, lots of masses and lots of temperatures. To keep them apart, they get a label underneath: Eₐ is the activation energy, mₑ the mass of the electron, T₁ and T₂ are two different temperatures. When the label doesn’t fit as a small letter, it’s written with an underscore: N_A is Avogadro’s number, the N with the label A.
Chemistry has one special case: in a formula like H₂O, the small number counts atoms. There are two hydrogens and one oxygen.
Real example · in the lesson What is a wall made of? Atoms and elements without fear
N_A = 6.022 140 76×10²³ mol⁻¹: Avogadro’s number, with its label A.
H° The ° for standard, which isn't degrees
- Say it
- ΔfH° is read “standard enthalpy of formation”.
- It means
- A little circle stuck to the top right of a quantity means “measured under standard conditions”, which have a reference pressure of 1 bar.
In chemistry, what a reaction gives depends on the pressure and on how concentrated everything is. To compare reactions fairly, values are given under reference conditions, the standard ones, and marked with °. IUPAC sets the standard pressure at 1 bar. Temperature isn’t part of the definition, but tables are usually given at 25 °C (298.15 K).
Real example · in the lesson Why doesn't diamond turn into graphite?
ΔᵣH° = Σν ΔfH°(products) − Σν ΔfH°(reactants): the heat of a reaction, under standard conditions.
Try it
Move both temperatures. Watch what happens to the sign of Δ when the final one ends up below the starting one.
Challenge
Sources
- Δ as a finite increment, subscripts and general notation: ISO 80000-2:2019, Quantities and units — Part 2: Mathematics (iso.org).
- Standard conditions (1 bar pressure), ΔᵣH and chemistry notation: IUPAC, Quantities, Units and Symbols in Physical Chemistry (“Green Book”), 3rd ed., 2007 (iupac.org).
How this cheat sheet was made: written with Claude’s help from the sources above and translated from the Spanish original. The examples are copied from the site’s lessons. The drawings are original.